December 4, 2025Angewandte ChemieOpen Access

A Crystalline Bismuth(II) Radical Anion: Synthesis, Characterization, and Reactivity

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Synthesis reveals a stable Bi(II) radical anion, with theoretical calculations suggesting significant radical reactivity.

Synthesis and characterization yield a stable Bi(II) radical anion, indicating unique electronic properties.
Key findings include enhanced radical behavior verified by X-ray absorption spectroscopy measurements.
Theoretical calculations support the radical's formation via one-electron transfer reactions and radical coupling.
Potential applications arise from the radical's unique electronic structure and reactivity in various chemical settings.

Pavlidis et al. (2025) studied this question.

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