Quantifying Å‐Scale Non‐Additive Solvation at Nanoparticle Interfaces

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This study demonstrates how solvent organization impacts nanoparticle behavior through SANS and Monte Carlo methods.

Non-additive solvation effects were quantified, revealing complex solvent behaviors at nanoparticle surfaces.
Maximal solvent clustering and ligand deformation were observed at the bulk azeotropic composition.
Small-angle neutron scattering was used alongside Monte Carlo reconstruction to analyze interfacial solvent structures.
These findings highlight significant deviations from classical core-shell models for solvent effects on nanoparticles.

Liu et al. (2025) studied this question.

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