Convergent Paired Electrolysis Enables Electrochemical Halogen-Atom Transfer-Mediated Alkyl Radical Cross-Coupling

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This approach demonstrates efficient cross-coupling using electrolysis, suggesting broader applications in synthetic chemistry.

The method enables efficient alkyl radical cross-coupling via electrochemical halogen-atom transfer.
Results show broad functional group tolerance with diverse alkyl iodides and aryl partners.
This transition-metal-free process facilitates selective radical-radical anion cross-coupling to produce various alcohols.
The protocol's scalability and application in modifying natural products highlight its significance in synthetic methods.

Sun et al. (2025) studied this question.

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View Full Paper

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Authors

This approach demonstrates efficient cross-coupling using electrolysis, suggesting broader applications in synthetic chemistry.

The method enables efficient alkyl radical cross-coupling via electrochemical halogen-atom transfer.
Results show broad functional group tolerance with diverse alkyl iodides and aryl partners.
This transition-metal-free process facilitates selective radical-radical anion cross-coupling to produce various alcohols.
The protocol's scalability and application in modifying natural products highlight its significance in synthetic methods.

Sun et al. (2025) studied this question.

View Full Paper

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Bookmark