Ru─B Modulated Electronic Structure Promotes Electrocatalytic Nitrate Reduction to Ammonia and Zinc‐Nitrate Battery

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DFT calculations reveal enhanced eNitRR activity in Ru-boron complexes, suggesting a novel approach for high-performance catalysts.

A maximum NH3 yield rate of 70.36 g h−1 g cat−1 was achieved, emphasizing the catalyst's effectiveness.
Faradaic efficiency reached 98.45%, showcasing the remarkable catalytic performance of Ru-B/CuxO.
Boron doping significantly alters the electronic structure of Ru, leading to enhanced catalytic activity and selectivity.
The Zn-NO3 battery using Ru-B/CuxO exhibits a high open-circuit voltage of 1.62 V, indicating its potential in energy applications.

Wang et al. (2025) studied this question.

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